How to Catch Rayquaza, Groudon, and Kyogre in Pokémon Emerald
Go to Sky Pillar, and press A in front of Rayquaza (who is at the top of the pillar)., Go to Sootopolis City., Use level 80+ Pokémon (Rayquaza is level 70), and you should have 50+ Ultra Balls (or, if you still have it, your Master Ball), and then...
Step-by-Step Guide
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Step 1: Go to Sky Pillar
A cutscene should play.
When it's is finished, press A in front of Rayquaza (at the Sky Pillar again), and then go into battle. , Paralysis is also an option, but Sleep lasts longer.
If you have it, attack using False Swipe. , If you're using your Master Ball, you probably need to lower the health to about half, but throwing a Master Ball when Rayquaza's health is red will almost always capture it. ,, He will tell you the route Groudon is on (randomized). , Make sure to bring level 55+ Pokémon, 50+ Ultra Balls, and 1 Master Ball (if you still have one).
Go into battle.
Put Groudon to Sleep, and then use Ultra Balls or a Master Ball. ,, Bring level 55+ Grass Pokémon, because Kyogre is an ice/water type Pokémon.
The same method applies mentioned above: put Kyogre to Sleep, lower it's health to red, and keep throwing Poké balls. -
Step 2: and press A in front of Rayquaza (who is at the top of the pillar).
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Step 3: Go to Sootopolis City.
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Step 4: Use level 80+ Pokémon (Rayquaza is level 70)
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Step 5: and you should have 50+ Ultra Balls (or
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Step 6: if you still have it
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Step 7: your Master Ball)
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Step 8: and then make Rayquaza fall asleep.
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Step 9: When Rayquaza's health bar turns red
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Step 10: throw Ultra Balls balls frequently.
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Step 11: Defeat Team Magma so that they release Groudon from captivity.
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Step 12: After defeating the Elite Four
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Step 13: go to the Weather Institute
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Step 14: and talk to the scientist on the topmost floor.
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Step 15: Go to the route the scientist mentioned (Groudon should be in a cave).
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Step 16: Defeat Team Aqua so that they release Kyogre.
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Step 17: Use Dive to get to Kyogre
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Step 18: because it is in an underwater cave.
Detailed Guide
A cutscene should play.
When it's is finished, press A in front of Rayquaza (at the Sky Pillar again), and then go into battle. , Paralysis is also an option, but Sleep lasts longer.
If you have it, attack using False Swipe. , If you're using your Master Ball, you probably need to lower the health to about half, but throwing a Master Ball when Rayquaza's health is red will almost always capture it. ,, He will tell you the route Groudon is on (randomized). , Make sure to bring level 55+ Pokémon, 50+ Ultra Balls, and 1 Master Ball (if you still have one).
Go into battle.
Put Groudon to Sleep, and then use Ultra Balls or a Master Ball. ,, Bring level 55+ Grass Pokémon, because Kyogre is an ice/water type Pokémon.
The same method applies mentioned above: put Kyogre to Sleep, lower it's health to red, and keep throwing Poké balls.
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